1, 2-Hydrogen migration and alkene formation in the photoexcited states of alkylphenyldiazomethanes

S Celebi, S Leyva, DA Modarelli…

文献索引：Celebi, Sol; Leyva, Soccoro; Modarelli, David A.; Platz, Matthew S. Journal of the American Chemical Society, 1993 , vol. 115, # 19 p. 8613 - 8620

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被引用次数: 59

摘要

Abstract: Laser flash photolysis of alkylphenyldiazomethanes in the presence of pyridine produces easily detected ylides. The data indicate that photolysis of alkylphenyldiazomethanes leads to both carbene formation and direct formation of rearrangement products which do not derive from relaxed carbene intermediates.