A Marcus treatment of rate constants for protonation of ring-substituted α-methoxystyrenes: intrinsic reaction barriers and the shape of the reaction coordinate

JP Richard, KB Williams

文献索引：Journal of the American Chemical Society, , vol. 129, # 21 p. 6952 - 6961

全文：HTML全文

被引用次数: 29

摘要

... Journal of the ... Soc. , 2007, 129 (21), pp 6952–6961. DOI: 10.1021/ja071007k. Publication Date (Web): May 9, 2007. Copyright © 2007 American Chemical Society. ... driving force for the reaction (ΔG°), (2) the intrinsic activation barrier Λ when ΔG° = 0 for the chemical portion of the ...