Aerobic Oxidation of Benzylic Halides to Carbonyl Compounds with Molecular Oxygen Catalyzed by TEMPO/KNO2 in Aqueous Media

…, F Yang, W Wei, F Sun, Z Yang, S Huang

文献索引：Liu, Qifa; Lu, Ming; Yang, Fei; Wei, Wei; Sun, Feng; Yang, Zhenbang; Huang, Sufeng Synthetic Communications, 2010 , vol. 40, # 8 p. 1106 - 1114

全文：HTML全文

被引用次数: 3

摘要

Benzylic halides were successfully oxidized to the corresponding aldehydes and ketones in good to excellent yields in aqueous media with molecular oxygen as oxidant in the presence of catalytic amounts of TEMPO (2, 2, 6, 6-tetramethylpiperidyl-1-oxy) and potassium nitrite (KNO2).