Structural and solid state 31P NMR studies of the four-coordinate copper (i) complexes [Cu (PPh 3) 3 X] and [Cu (PPh 3) 3 (CH 3 CN)] X
…, PC Healy, GA Bowmaker, BW Skelton, AH White
文献索引:Hanna, John V.; Boyd, Sue E.; Healy, Peter C.; Bowmaker, Graham A.; Skelton, Brian W.; White, Allan H. Dalton Transactions, 2005 , # 15 p. 2547 - 2556
The tris (triphenylphosphine) copper (I) complexes [(PPh3) 3CuX] for X= Cl (1), Br (2), I (3), ClO4 (4), BF4 (5),[(PPh3) 3CuCl]· CH3CN (1a),[Cu (PPh3) 3 (CH3CN)] X for X= ClO4 (6), BF4 (7), and [Cu (PPh3) 3 (CH3CN)] X· CH3CN for X= SiF5 (8), PF6 (9) have been studied by solid state 31P CP/MAS NMR spectroscopy together with single crystal X-ray diffraction for compounds (6)–(9), the latter completing the availability of crystal structure data for the ...