Ruthenium??Catalyzed Remote Electronic Activation of Aromatic C F Bonds

AJA Watson, BN Atkinson, AC Maxwell…

文献索引：Watson, Andrew J. A.; Atkinson, Benjamin N.; Maxwell, Aoife C.; Williams, Jonathan M. J. Advanced Synthesis and Catalysis, 2013 , vol. 355, # 4 p. 734 - 740

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被引用次数: 6

摘要

Abstract The tandem isomerization and nucleophilic aromatic substitution of allylic fluoro- substituted benzylic alcohols is described for the first time. In the presence of the ruthenium complex Ru (PPh 3) 3 (CO)(H) 2, 1-(4-fluorophenyl) prop-2-en-1-ol is converted into the corresponding para-amino ketone or para-phenolic substituted ketone.