Chemistry letters

Electrochemical deacetylation of 1, 3-dicarbonyl compounds

K Fujimoto, H Maekawa, Y Matsubara, I Nishiguchi

文献索引：Fujimoto, Kazuo; Maekawa, Hirofumi; Matsubara, Yoshiharu; Nishiguchi, Ikuzo Chemistry Letters, 1996 , # 2 p. 143 - 144

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被引用次数: 3

摘要

抄録 Mild deacetylation of 1, 3-dicarbonyl compounds was achieved by halonium-ion mediated electrolysis. In this reaction, the supporting electrolyte including sodium halide NaX (X= Cl or Br) was essential since the reaction proceeded through substitution by a halonium ion, generated electrochemically at anode, on active methine carbons followed by base-catalyzed deacetylation, and was terminated by reductlve dehalogenation of the ...