Hydration of Propargylic Alcohols by Ruthenium Catalysts, with Dominant Anti??Markovnikov Regioselectivity, Formation of α, β??Unsaturated Products and Catalytic …

N d'Alessandro, M Di Deo, M Bonetti…

文献索引：D'Alessandro, Nicola; Di Deo, Milena; Bonetti, Monica; Tonucci, Lucia; Morvillo, Antonino; Bressan, Mario European Journal of Inorganic Chemistry, 2004 , # 4 p. 810 - 817

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被引用次数: 7

摘要

Abstract Ruthenium catalysts—water-soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hydroxyapatite complexes—proved to be effective for the hydration of propargylic alcohols in entirely aqueous media. 1-Phenyl-2-propyn-1-ol underwent an unprecedented catalytic hydration-decarbonylation-dehydration reaction, giving rise to styrene and carbon monoxide; 2-propyn-1-ol and 3-butyn-2-ol gave ...