Multiple rearrangements of 1-methoxyfluorenylidene to 1-phenanthrenol

H Tomioka, N Kobayashi, Y Ohtawa…

文献索引：Tomioka, Hideo; Kobayashi, Noriyuki; Ohtawa, Yasuki; Murata, Shigeru Journal of Organic Chemistry, 1991 , vol. 56, # 8 p. 2609 - 2611

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被引用次数: 1

摘要

Summary: Flash vacuum pyrolysis of 1-methoxy-9-diazofluorene (1) yielded 1- phenanthrenol (2). Experiments with'%-and'%-labeled 1 revealed that the source of Clo of 2 is the methoxy carbon of 1, whereas the likely source of Cg of 2 is the diazo-substituted carbon of 1.