Journal of the American Chemical Society

Oxidation of allylic radicals by electron transfer: effect of complex copper salts

JK Kochi

文献索引：Kochi,J.K. Journal of the American Chemical Society, 1962 , vol. 84, p. 3271 - 3277

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被引用次数: 39

摘要

Introduction Previous studies2s3 have shown that t-butyl peresters, t-butyl hydroperoxides and peroxides react with cuprous salts to produce t-butoxy radicals (1). In the presence of alkenes these alkoxy radicals produce allylic radicals I by hydrogen abstraction (2); and with conjugated dienes such as butadiene, isoprene and styrene they react by addition (3) to form such adducts as the allylic t-butoxybutenyl radicals 11. Allylic radicals produced ...