Allylic oxidation of olefins by mercuric acetate

Z Rappoport, S Winstein, WG Young

文献索引：Rappoport,Z. et al. Journal of the American Chemical Society, 1972 , vol. 94, p. 2320 - 2329

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被引用次数: 37

摘要

Abstract: Both the oxidation of allylbenzene by Hg (OAc)? and the solvolysis of cinnamylmercuric acetate give 40x a-phenylallyl acetate and 60% cinnamyl acetate. The solvolysis of crotylmercuric acetate and the oxidations of 1-and 2-olefins C, H2, by Hg (OAc) 2 give under kinetic control exclusively the secondary allylic esters. The oxidation rate is apparently first order in the olefin-Hg (OAc) 2 adduct. Rate-determining formation of the ...