The Reaction of Aldoketene Dimers with Grignard Reagents1

DV NIGHTINGALE…

文献索引：Nightingale,D.V.; Turley,R.H. Journal of Organic Chemistry, 1961 , vol. 26, p. 2656 - 2658

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被引用次数: 2

摘要

When an excess of phenylmagnesium bromide reacted with n-butylketene dimer, two simple ketones, 6-undecanone and benzophenone, and a di-addition compound, 5-( diphenylhydroxyniethyl)-6-~ ndecanone, were isolated from the reaction products. Analogous compounds were obtained from phenylmagnesium bromide and n-octylketene dimer, but from n-hexylketenedimer, the only identified product isolated from the reaction ...