A highly catalytic and selective conversion of carboxylic acids to 1-alkenes of one less carbon atom

JA Miller, JA Nelson, MP Byrne

文献索引：Miller, Joseph A.; Nelson, Jeffrey A.; Byrne, Michael P. Journal of Organic Chemistry, 1993 , vol. 58, # 1 p. 18 - 20

全文：HTML全文

被引用次数: 45

摘要

Summary: An equimolar mixture of a carboxylic acid and acetic anhydride produces a reagent combination that undergoes a highly efficient decarbonylationtdehydration at 250 OC using either Pd-or Rh-based catalyst systems, affording excellent yields of the corresponding 1-alkenes of one less carbon atom.