Dioxiranes. 20. Preparation and properties of some new dioxiranes

RW Murray, M Singh, R Jeyaraman

文献索引：Murray, Robert W.; Singh, Megh; Jeyaraman, Ramasubbu Journal of the American Chemical Society, 1992 , vol. 114, # 4 p. 1346 - 1351

全文：HTML全文

被引用次数: 62

摘要

Abstract: The in situ method for producing dioxiranes has been modified to permit the isolation in ketone solution of some nonvolatile dioxiranes. The dioxiranes have been characterized spectroscopically and, in some cases, by chemical reactions. ... Introduction In 1985 we described* the isolation in solution of dimethyl- dioxirane (1) as well as some related dioxiranes. Dimethyl- dioxirane is a powerful oxygen atom donor, and the availability of this unique reagent in solution ...