Tetrahedron letters

A convenient, one-pot conversion of secondary alcohols to esters via a tandem oxidation-Baeyer-Villiger sequence

ML Morin-Fox, MA Lipton

文献索引：Morin-Fox, Michelle L.; Lipton, Mark A. Tetrahedron Letters, 1992 , vol. 33, # 39 p. 5699 - 5700

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被引用次数: 5

摘要

Absbtwt: A one-p01 reoction sequence has been developed which converts secondary alcohals to esters via oxidahn to the carbonvl conwound and concomitant Baever-Villker reaction. This orocedure emdow me& chloroperoxyvhenzok acid (mCPBA) as the prinkry ox&t in both steps a& a catalytic~ amknt of a cyclic Cr (VI) ester as a co-okabt in the inSal step. Isolated yiellir are rypicolly vety high and chromatographic pw@ ication of the crude ...