Hypervalent Iodine Oxidants: Structure and Kinetics of the Reactive Intermediates in the Oxidation of Alcohols and 1, 2-Diols by o-Iodoxybenzoic Acid (IBX) and Dess- …

…, M Frigerio, M Santagostino

文献索引：Munari, Sergio De; Frigerio, Marco; Santagostino, Marco Journal of Organic Chemistry, 1996 , vol. 61, # 26 p. 9272 - 9279

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被引用次数: 135

摘要

Alcohols and 1, 2-diols oxidation by o-iodoxybenzoic acid (IBX) has been examined by 1H- NMR spectroscopy. Reversible formation of reactive intermediates, iodic esters 5, has been observed, and their structures in DMSO-d 6 solution have been defined as 10-I-4 axial alkoxyiodinane oxides by comparison of the chemical shift difference data with those obtained for Dess-Martin periodinane (DMP)-alcoholate and-diolate adducts. The ...

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