Chemistry of oxaziridines. 1. Synthesis and structure of 2-arenesulfonyl-3-aryloxaziridines. A new class of oxaziridines

…, J Lamendola Jr, U Nadir, EW Kluger…

文献索引：Davis, Franklin A.; Lamendola, Joseph; Nadir, Upender; Kluger, Edward W.; Sedergran, Thomas C.; et al. Journal of the American Chemical Society, 1980 , vol. 102, # 6 p. 2000 - 2005

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被引用次数: 129

摘要

Abstract: A new class of oxaziridine derivatives, 2-arenesulfonyl-3-aryloxaziridines (2), is prepared by m-CPBA oxidation of sulfonimines (RSOlN= CHAr). These compounds are the first stable examples of this ring system to have a substituent other than carbon attached to nitrogen and are characterized by a highly electrophilic oxaziridine oxygen atom. These oxaziridines have the E configuration as determined by X-ray crystallography. The ...