An efficient deprotective method for allylic alcohols protected as methoxyethoxymethyl (MEM) and methoxymethyl (MOM) ethers

…, G Leandri, M Klos-Ringuet, C Corriol

文献索引：Monti, H.; Leandri, G.; Klos-Ringuet, M.; Corriol, C. Synthetic Communications, 1983 , vol. 13, # 12 p. 1021 - 1026

全文：HTML全文

被引用次数: 79

摘要

Abstract Methoxyethoxymethyl ethers (MEM) and methoxymethyl ethers (MOM) of allylic alcohols are readily cleaved by pyridinium paratoluenesulfonate (PPTS) in 2-butanone or t- butyl alcohol. This procedure is also efficient for deprotection of benzylic and aliphatic alcohols.

~97%

~95%

~95%

~99%

~91%

~95%

~98%

~97%

Reductions of aliphatic and aromatic nitriles to primary ami...

[Pasumansky, Lubov; Haddenham, Dustin; Clary, Jacob W.; Fisher, Gary B.; Goralski, Christian T.; Singaram, Bakthan Journal of Organic Chemistry, 2008 , vol. 73, # 5 p. 1898 - 1905]

Tandem hydroformylation/hydrogenation of alkenes to normal a...

[Diab, Lisa; Smejkal, Tomas; Geier, Jens; Breit, Bernhard Angewandte Chemie - International Edition, 2009 , vol. 48, # 43 p. 8022 - 8026]

Silica gel supported zinc borohydride. A novel reagent for h...

[Ranu, Brindaban C.; Sarkar, Arunkanti; Saha, Manika; Chakraborty, Rupak Tetrahedron, 1994 , vol. 50, # 22 p. 6579 - 6584]

Selective reduction of aldehydes via BINOL–Zr complex

[Lorca, Miguel; Kuhn, Dan; Kurosu, Michio Tetrahedron Letters, 2001 , vol. 42, # 36 p. 6243 - 6246]

Hydrogenation and hydrogenolysis with Pd/C in poly (ethylene...

[Chandrasekhar; Shyamsunder; Chandrashekar; Narsihmulu Synlett, 2004 , # 3 p. 522 - 524]