Stereodynamics of diethylmethylamine and triethylamine

CH Bushweller, SH Fleischman, GL Grady…

文献索引：Bushweller, C. Hackett; Fleischman, Stephen H.; Grady, Gilbert L.; McGoff, Paul; Rithner, Christopher D.; et al. Journal of the American Chemical Society, 1982 , vol. 104, # 23 p. 6224 - 6236

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被引用次数: 1

摘要

Abstract: Diethylmethylamine is the simplest acyclic trialkylamine that possesses the requisite symmetry that allows, in principle, the direct observation of both nitrogen inversion and isolated nitrogen-carbon bond rotation using 'H dynamic nuclear magnetic resonance (DNMR) spectroscopy. DNMR studies of diethylmethylamine and two deuterated derivatives complemented by empirical force-field calculations reveal a comprehensive picture of the ...