Chemistry–A European Journal

Sulfoximines: A Reusable Directing Group for Chemo??and Regioselective ortho C H Oxidation of Arenes

MR Yadav, RK Rit, AK Sahoo

文献索引：Yadav, M. Ramu; Rit, Raja K.; Sahoo, Akhila K. Chemistry - A European Journal, 2012 , vol. 18, # 18 p. 5541 - 5545

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被引用次数: 67

摘要

The directing-group-assisted, transition-metal-catalyzed CÀH oxidation of arenes is recognized as an elegant and versatile approach for the synthesis of useful phenol derivatives.[1, 2] The ability of the directing group (DG) to coordinate the transition metal triggers the activation of the remote CÀH bond and facilitates the formation of the product with better regioselectivity.[3] The Sanford and Yu groups have explored the ...