Utilisation de membranes echangeuses d'ions en electrosynthese organique.: V. Additions de michael induites par des bases électrogénérées au contact d'un …
E Raoult, J Sarrazin, A Tallec
文献索引：Raoult, Eugene; Sarrazin, Jean; Tallec, Andre Tetrahedron, 1987 , vol. 43, # 22 p. 5299 - 5306
The addition of carbon acids to acrylonitrile or methyl acylate can be initiated by means of bases electrogenerated in aprotic media in the absence of supporting-electrolyte, at the interface between a porous cathode and a solid polymer electrolyte. The consumption of electricity is below 10-2 faraday per mole. Putting to the test donors with decreasing acidity (2-nitropropane, malononitrile, diethyl malonate, ethyl cyanacetate, 2- ...
