Unusual reaction course of styrenes to 2-arylethyltriphenylphosphonium salts

K Okuma, K Yoshitake, T Izaki, K Yoshida…

文献索引：Okuma, Kentaro; Yoshitake, Koichiro; Izaki, Toshiharu; Yoshida, Keiko; Shioji, Kosei Bulletin of the Chemical Society of Japan, 2007 , vol. 80, # 9 p. 1785 - 1790

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被引用次数: 3

摘要

1-Arylethyltriphenylphosphonium bromides thermally rearranged to 2- arylethyltriphenylphosphonium bromides. Direct formation of 2-arylethylphosphonium bromides was achieved by reacting styrene, HBr, and triphenylphosphine. On the other hand, thermolysis of 1-indanyltriphenylphosphonium bromide gave indene and triphenylphosphonium bromide. From deuterium and 13 C-labeled experiments, the ...