Journal of organometallic chemistry

Electrosynthesis of heteroaromatic aldehydes by palladium-catalyzed carbonylation of heteroaromatic iodides in the presence of formic acid

I Chiarotto, M Feroci

文献索引：Chiarotto, Isabella; Feroci, Marta Journal of Organometallic Chemistry, 2006 , vol. 691, # 11 p. 2589 - 2592

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被引用次数: 5

摘要

The palladium-catalyzed electrocarbonylation of heteroaromatic iodides, performed in the presence of formic acid under one atmosphere of carbon monoxide, affords heteroaromatic aldehydes in moderate to good yields. It has been developed a new application of palladium- catalyzed formylation using carbon monoxide, formic acid and tertiary amines as ligands under electrochemical reducing conditions.