Semiconductor photocatalysis. 8. Zinc sulfide-catalyzed photoreduction of aldehydes and related derivatives: two-electron-transfer reduction and relationship with …
…, Y Ishimaru, Y Miyake, T Shiragami, C Pac…
文献索引：Yanagida, Shozo; Ishimaru, Yoshiteru; Miyake, Yoshio; Shiragami, Tsutomu; Pac, Chyongjin; et al. Journal of Physical Chemistry, 1989 , vol. 93, # 6 p. 2576 - 2582
Photocatalytic activity and spectroscopic properties of ZnS suspensions for the two-electron reduction of aldehydes or related compounds in aqueous medium are described. The ZnS suspension (ZnS-0) prepared by cooling from aqueous ZnSOl and Na2S solutions catalyzes photoredox reactions of acetaldehyde, giving ethanol without much H2 evolution as a two- electron-reduction product, and acetic acid, biacetyl, and acetoin as oxidation products. ...
