Advanced Synthesis & Catalysis

Acceptorless and Base??Free Dehydrogenation of Alcohols and Amines using Ruthenium??Hydride Complexes

S Muthaiah, SH Hong

文献索引：Muthaiah, Senthilkumar; Hong, Soon Hyeok Advanced Synthesis and Catalysis, 2012 , vol. 354, # 16 p. 3045 - 3053

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被引用次数: 32

摘要

Abstract An efficient, operatively simple, acceptorless, and base-free dehydrogenation of secondary alcohols and nitrogen-containing heterocyclic compounds was achieved by using readily available ruthenium hydride complexes as precatalysts. The complex RuH 2 (CO)(PPh 3) 3 (1) and Shvo's complex (2) showed excellent activities for the dehydrogenation of secondary alcohols and nitrogen containing heterocycles. In addition ...