Journal of the American Chemical Society

Aromatic haloethylation with palladium and copper halides

RF Heck

文献索引：Heck,R.F. Journal of the American Chemical Society, 1968 , vol. 90, p. 5538 - 5542

被引用次数: 135

摘要

Abstract: Aryl derivatives of group VI11 metal compounds, prepared from group VI11 metal salts and mercury, tin, or lead aryls, react with olefins in the presence of cupric halides to form 2-arylethyl halides. Chlorides are formed in higher yields than bromides. The most generally useful and readily obtainable reactants were arylmercuric halides, with lithium palladium chloride as the group VI11 metal compound. Since only catalytic amounts of the ...

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