A general synthesis of vinylic fluorides

…, RN Zuckermann, WS Johnson

文献索引：Daub, G. William; Zuckermann, Ronald N.; Johnson, William S. Journal of Organic Chemistry, 1985 , vol. 50, # 10 p. 1599 - 1602

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摘要

A number of approaches to the vinylic fluoride moiety have been developed. They involve (1) the elimination of the elements of HF from a difluoro compound with alumina:(2) the reductive elimination of fluoride and halide from an a-halo gem-difluoride with a metal reducing agent, 1-13 (c) the ring opening of gem-chlorofluorocyclopropanes, 14 (d) the condensation reactions of aldehydes and ketones with fluorinated nu~ leophiles,~~ J~ ...

~57%

~49%

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