Steric Factors in Liquid-Phase Oxidation of Olefins with iso Structure

AV Voronenkov, NA Simonov, OP Yablonskii…

文献索引：Voronenkov; Simonov; Yablonskii; Koshel' Russian Journal of Organic Chemistry, 2001 , vol. 37, # 3 p. 318 - 320

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摘要

Abstract Products of liquid-phase oxidation of 2-methyl-2-butene and 2-methyl-2-pentene were studied by NMR and IR spectroscopy. Steric hindrances in liquid-phase oxidation of olefins with iso structure were shown to arise from branching of the alkyl group at the α- carbon atom.