Steric Factors in Liquid-Phase Oxidation of Olefins with iso Structure

AV Voronenkov, NA Simonov, OP Yablonskii…

Index: Voronenkov; Simonov; Yablonskii; Koshel' Russian Journal of Organic Chemistry, 2001 , vol. 37, # 3 p. 318 - 320

Full Text: HTML

Citation Number: 0

Abstract

Abstract Products of liquid-phase oxidation of 2-methyl-2-butene and 2-methyl-2-pentene were studied by NMR and IR spectroscopy. Steric hindrances in liquid-phase oxidation of olefins with iso structure were shown to arise from branching of the alkyl group at the α- carbon atom.

Time-resolved observation of sequential bond cleavage in a g...

[Adams, J. Stephen; Burton, Katherine A.; Andrews, B. Kim; Weisman, R. Bruce; Engel, Paul S. Journal of the American Chemical Society, 1986 , vol. 108, # 25 p. 7935 - 7938]

The reactions of t-butoxyl with unsaturated hydrocarbons: St...

[Cuthbertson, Matthew J.; Rizzardo, Ezio; Solomon, David H. Australian Journal of Chemistry, 1983 , vol. 36, # 10 p. 1957 - 1973]

Radikal??Stabilisierungsenergie–das MMEVBH??Kraftfeld

[Roth, Wolfgang R.; Staemmler, Volker; Neumann, Martin; Schmuck, Carsten Liebigs Annalen, 1995 , # 6 p. 1061 - 1118]