Application of a novel 1, 3-diol with a benzyl backbone as chiral ligand for asymmetric oxidation of sulfides to sulfoxides

P Gogoi, T Kotipalli, K Indukuri, S Bondalapati…

文献索引：Gogoi, Paramartha; Kotipalli, Trimurthulu; Indukuri, Kiran; Bondalapati, Somasekhar; Saha, Pipas; Saikia, Anil K. Tetrahedron Letters, 2012 , vol. 53, # 22 p. 2726 - 2729

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被引用次数: 8

摘要

Optically active sulfoxides are not only important in organic synthesis as chiral auxiliaries 1 but also important chiral ligands in asymmetric synthesis. 2 Chiral sulfoxides are also found in many natural products and pharmaceuticals. 3 There are two different types of chemical approaches namely direct and indirect methods for their syntheses. The indirect method consists of the synthesis of a sulfinylating agent with an electrophilic sulfur of known configuration, followed by ...