Tetrahedron letters

Hydroalkoxylation of non-activated olefins catalysed by Lewis superacids in alcoholic solvents: an eco-friendly reaction

P Lemechko, F Grau, S Antoniotti, E Duñach

文献索引：Lemechko, Pierre; Grau, Fanny; Antoniotti, Sylvain; Dunach, Elisabet Tetrahedron Letters, 2007 , vol. 48, # 33 p. 5731 - 5734

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被引用次数: 34

摘要

Electron-rich C–C multiple bonds such as alkynes, 1 allenes, 2 and 3 and in some cases alkenes 4 can be activated by metal-based catalysts and undergo functionalisation by heteronucleophiles. To facilitate the nucleophilic attack to alkenes, a polarisation of the double bond is often required, for example, by conjugation with a carbonyl function, 5 and 6 another double bond, 7 or an arene. 8 and 9 The lack of reactivity of non-activated olefins towards ...