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Bulletin of the Chemical Society of Japan

Dissociative electron capture of hydrogen-bonded hydroxy groups: molecular dynamics and matrix isolation ESR study

PH Kasai

文献索引:Kasai, Paul H. Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 3 p. 254 - 260

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被引用次数: 2

摘要

While examining PFPE (perfluoropolyether)-based disk lubricants, extra lability was suspected for a hydrogen-bonded pair of hydroxy end-groups in the presence of a nucleophile (electron donor). Plausible reaction sequences upon electron capture of hydrogen-bonded methanol dimer, hydrogen-bonded ethanol dimer, and 1, 2-propanediol were first examined by a molecular dynamics method based on the potential given by a ...