One-electron reduction of N-bromosuccinimide. Rapid expulsion of a bromine atom

J Lind, X Shen, TE Eriksen, G Merenyi…

文献索引：Lind, Johan; Shen, Xinhua; Eriksen, Trygve E.; Merenyi, Gabor; Eberson, Lennart Journal of the American Chemical Society, 1991 , vol. 113, # 12 p. 4629 - 4633

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被引用次数: 25

摘要

Abstract: By means of pulse radiolysis N-bromosuccinimide, SBr, was reduced to its radical anion, SBr'. Evidence is presented that SBr'-rapidly fragments into the succinimide anion, S-, and a free bromine atom, Br', which is converted into Br2'-by reacting with Br-present. The rate constant of hydrogen abstraction by Br'from 2-propanol and methanol have been determined. The carbon-centered radical of tert-butyl alcohol was also found to react with ...