Synthetic Communications

Regioselective Allylation of Ketones

RA Cormier, TE Morris

文献索引：Cormier, Russell A.; Morris, Theresa E. Synthetic Communications, 1987 , vol. 17, # 14 p. 1673 - 1676

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被引用次数: 3

摘要

Abstract In connection with our work concerning synthesis of insect pheromones, 1 we became interested in reports by Lorette and Howard2 in which were described a method for preparing alpha-allyl ketones. These authors reported that diallyl ketals (4), available by exchange between a ketone (1), allyl alcohol and 2, 2-dimethoxypropane, suffer acid- catalyzed elimination to yield intermediate allyl enol ethers (5/6) which undergo ...