Recueil des Travaux Chimiques des Pays-Bas

The migration of the diphenylmethyl and benzyl groups in phenol

J van Alphen

文献索引：van Alphen Recueil des Travaux Chimiques des Pays-Bas, 1927 , vol. 46, p. 802

全文：HTML全文

被引用次数: 0

摘要

Eight grams of 4-hydroxy-triphenylcarbinol were dissolved in 40 ccs. glacial acetic acid and reduced in the boiling solution with zinc dust. After filtration the 4-hydroxytriphenylmethane was precipitated by dilution with water. The product melted at 111O after dissolving in benzene and reprecipitating with light petroleum, whilst a mixed melting point with fraction B gave 109O 30 that this also consisted of 4-hydroxy-triphenylmethane.