Synlett

A New Application of Hypervalent Iodine (λ5) Reagents with Organosulfonic Acids for Direct α-Organosulfonyloxylation Carbonyl Compounds

US Mahajan, KG Akamanchi

文献索引：Mahajan, Ulhas S.; Akamanchi, Krishnacharya G. Synlett, 2008 , # 7 p. 987 - 990

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被引用次数: 6

摘要

Abstract Hypervalent iodine (λ 5) reagents in combination with p-toluenesulfonic acid when reacted with ketones under reflux temperature in acetonitrile gave α-tosyloxy ketones in moderate to excellent yields. The reaction was developed further for both ketones and dicarbonyl compounds using Dess-Martin periodinane reagent in combination with p- toluenesulfonic acid and methanesulfonic acid, to give mono-α-tosyloxy and mono-α- ...