Tetrahedron

Palladium-catalyzed hydrogenation with use of ionic liquid bis (2-hydroxyethyl) ammonium formate [BHEA][HCO 2] as a solvent and hydrogen source

…, S Yoshioka, A Igesaka, H Nishioka, Y Takeuchi

文献索引：Suzuki, Hideyuki; Yoshioka, Seiki; Igesaka, Ami; Nishioka, Hiromi; Takeuchi, Yasuo Tetrahedron, 2013 , vol. 69, # 31 p. 6399 - 6403

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被引用次数: 4

摘要

We designed ionic liquid bis (2-hydroxyethyl) ammonium formate [BHEA][HCO2] for use as a solvent and hydrogen donor for hydrogenation. Catalytic hydrogenation of aromatic ketones, nitro groups, and olefins with PdCl2 in [BHEA][HCO2] generated the corresponding reduction products. Selective reduction of aromatic ketones over aliphatic ketones was observed. Hydrogenolysis of benzyl ethers and benzyl amines also proceeded. All these ...