Journal of the American Chemical Society

Diaryltetraoxypersulfuranes: preparation, characterization, and reactions

WY Lam, JC Martin

文献索引：Lam, William Y.; Martin, J. C. Journal of the American Chemical Society, 1981 , vol. 103, # 1 p. 120 - 127

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被引用次数: 14

摘要

Abstract: Diarylbis (acy1oxy) dialkoxypersulfurane 7, the fist example of a hexacoordinate organosulfur (V1) derivative lacking fluorine ligands, a sulfone bisketal, was synthesized by treatment of sulfide diol diacid 6 with pyridine and tert-butyl hypochlorite at 0 “C. Persulfurane 7 is stable in crystalline form and unreactive toward atmospheric moisture. It rapidly decomposes at room temperature in ordinary chloroform to give isomeric sulfone ...