Synthesis of perfluorinated allylic compounds by radical allylation and their purification over fluorous reverse-phase silica

…, S Kreimerman, T Niguma, S Minakata, M Komatsu…

文献索引：Ryu, Ilhyong; Kreimerman, Sergio; Niguma, Tatsuro; Minakata, Satoshi; Komatsu, Mitsuo; Luo, Zhiyong; Curran, Dennis P. Tetrahedron Letters, 2001 , vol. 42, # 5 p. 947 - 950

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被引用次数: 47

摘要

A simple free-radical method for the preparation of a variety of perfluorinated allylic compounds has been developed starting from perfluoroalkyl iodides and allyltins. Allyltributyltin, methallyltributyltin and crotyltributyltin all proved to be useful for the transformation. The desired perfluorinated allylic compound was conveniently isolated from the crude mixture by solid-phase extraction with fluorous reverse-phase silica (FRPS).