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Regioselective Synthesis of Functionalized 3-(Methylthio) phenols by the First Formal [3+ 3] Cyclocondensations of 1, 3-Bis (trimethylsilyloxy)-1, 3-butadienes with 1, 1 …

…, R Klassen, T Trabhardt, A Villinger, P Langer

文献索引:Lubbe, Mathias; Klassen, Renske; Trabhardt, Tiana; Villinger, Alexander; Langer, Peter Synlett, 2008 , # 15 p. 2331 - 2333

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被引用次数: 12

摘要

Chan and coworkers developed [¹6] a convenient synthesis of salicylates by cyclocondensation of 1,3-bis(silyl enol ethers) [¹7] with 3-silyloxy-2-en-1-ones. In recent years, we have extended the scope of this chemistry and studied its application to the synthesis of a variety of functionalized arenes. [¹8] For example, we have reported formal [3+3] cyclocondensations of 1,3-bis(silyl enol ethers) with 1,1,3,3-tetraalkoxypropanes. [¹9] 3-Alkoxy-1-aryl-2-en-1-ones and 3-alkoxy-1- ...