Is triquinacene homoaromatic? A thermochemical answer in the affirmative

JF Liebman, LA Paquette, JR Peterson…

文献索引：Liebman, Joel F.; Paquette, Leo A.; Peterson, John R.; Rogers, Donald W. Journal of the American Chemical Society, 1986 , vol. 108, p. 8267 - 8268

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被引用次数: 42

摘要

Following exhaustive catalytic hydrogenation, the saturated exo alcohol was oxidized with the chromium trioxidepyridine complex in dichloromethane and reduced with lithium aluminum hydride to the endo isomer. 1 Conversion to the mesylate and E2 elimination on activated alumina delivered the known hydrocarbon," which was brought to analytical purity by preparative VPC as before.