Silver (1+) ion catalyzed rearrangements. XXXII. Unsaturated heterocyclic systems. XCIII. Probing of the interrelation between heteroatomic substitution and …

LA Paquette, RK Russell…

文献索引：Paquette,L.A. et al. Journal of the American Chemical Society, 1975 , vol. 97, # 21 p. 6124 - 6134

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被引用次数: 15

摘要

Abstract: To assess the magnitude and direction of equilibrium caused by certain electronegative atoms, three 2, 8-annulated semibullvalenes have been synthesized. These molecules are directly patterned in structure after the 2.8-trimethylene bridged hydrocarbon which was known to exhibit approximately equal partiality for the two valence tautomeric forms at room temperature. For the three cases where the central methylene group was ...