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Atmospheric aqueous phase radical chemistry of the isoprene oxidation products methacrolein, methyl vinyl ketone, methacrylic acid and acrylic acid–kinetics and …

…, J Schindelka, E Szeremeta, T Schaefer…

文献索引:Schoene, Luisa; Schindelka, Janine; Szeremeta, Edyta; Schaefer, Thomas; Hoffmann, Dirk; Rudzinski, Krzysztof J.; Szmigielski, Rafal; Herrmann, Hartmut Physical Chemistry Chemical Physics, 2014 , vol. 16, # 13 p. 6257 - 6272

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被引用次数: 17

摘要

Kinetic and mechanistic studies were conducted on the isoprene oxidation products methacrolein, methyl vinyl ketone, methacrylic and acrylic acid reacting with hydroxyl and nitrate radicals and sulfate radical anions in aqueous solution by use of the laser flash photolysis technique and a reversed-rate method for kinetics. High-performance liquid chromatography/mass spectrometry was applied for product analysis. The kinetic ...