Atmospheric aqueous phase radical chemistry of the isoprene oxidation products methacrolein, methyl vinyl ketone, methacrylic acid and acrylic acid–kinetics and …

…, J Schindelka, E Szeremeta, T Schaefer…

Index: Schoene, Luisa; Schindelka, Janine; Szeremeta, Edyta; Schaefer, Thomas; Hoffmann, Dirk; Rudzinski, Krzysztof J.; Szmigielski, Rafal; Herrmann, Hartmut Physical Chemistry Chemical Physics, 2014 , vol. 16, # 13 p. 6257 - 6272

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Citation Number: 17

Abstract

Kinetic and mechanistic studies were conducted on the isoprene oxidation products methacrolein, methyl vinyl ketone, methacrylic and acrylic acid reacting with hydroxyl and nitrate radicals and sulfate radical anions in aqueous solution by use of the laser flash photolysis technique and a reversed-rate method for kinetics. High-performance liquid chromatography/mass spectrometry was applied for product analysis. The kinetic ...