Electrochemical reduction of 1-iodo-5-decyne and 1-bromo-5-decyne at mercury cathodes in dimethylformamide

…, JA Cleary, DM La Perriere, DG Peters

文献索引：Shao, Rui-lian; Cleary, James A.; Perriere, Daniel M. La; Peters, Dennis G. Journal of Organic Chemistry, 1983 , vol. 48, # 19 p. 3289 - 3294

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被引用次数: 17

摘要

Pulse polarograms for 1-iodo-5-decyne in dimethylformamide containing tetramethylammonium perchlorate exhibit two waves. At potentials corresponding to the first wave, electrolysis of 1-iodo-5-decyne at mercury results in 5-decynyl radicals that (i) adsorb onto and interact with the mercury electrode to give 5-decynylmercury radicals which disproportionate into di-bdecynylmercury or (ii) cyclize and then accept a hydrogen atom ...