Photochemistry of (. eta. 1-C5Cl5) Mn (CO) 5 and (. eta. 1-C6H5CH2) Mn (CO) 5: competitive formation of 16-and 17e intermediates

KM Young, MS Wrighton

文献索引：Young; Wrighton Journal of the American Chemical Society, 1990 , vol. 112, # 1 p. 157 - 166

被引用次数: 18

摘要

Abstract: Irradiation of RMn (CO) s (R= q'-CsCIs, q1-C6HsCH2) in alkane glasses at 95 K leads to CO loss as the only detectable photoprocess: the ring-slipped (q3-CSCIS) Mn (CO), and (qs-CsC1S) Mn (C0) 3 or (q3-C6HsCH,) Mn (CO), are formed, respectively. The identities of the q3 intermediates from (q'-C5CIS) Mn (CO) S and (q'-C6HSCH2) Mn (CO) s have been established by spectroscopic means and by chemical-trapping experiments. ...

38117-54-3

环戊基铁(II) 二羰基二聚体

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