Polyhedron

Reactivity studies on some η 1-alkenyl complexes of iron

L Hermans, SF Mapolie

文献索引：Hermans, Leone; Mapolie, Selwyn F. Polyhedron, 1997 , vol. 16, # 5 p. 869 - 875

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被引用次数: 12

摘要

The 1-alkenyl complexes 5-C5H5 (CO) 2Fe (CH2) nCH CH2](n= 2 and 3) have been prepared by the reaction of Na [η5-C5H5 (CO) 2Fe] with 4-bromo-l-butene and 5-bromo-l- pentene respectively. The reactivity of the σ-olefin complexes in hydrogenation, hydroboration and hydroformylation reactions are reported as are reactions with Lewis acids such as TiCl4 and the electrophile HC1.