Mechanism of the sulfurisation of phosphines and phosphites using 3-amino-1, 2, 4-dithiazole-5-thione (xanthane hydride)
J Hanusek, MA Russell, AP Laws, P Jansa…
文献索引：Hanusek, Jiri; Russell, Mark A.; Laws, Andrew P.; Jansa, Petr; Atherton, John H.; Fettes, Kevin; Page, Michael I. Organic and Biomolecular Chemistry, 2007 , vol. 5, # 3 p. 478 - 484
Contrary to a previous report, the sulfurisation of phosphorus (III) derivatives by 3-amino-1, 2, 4-dithiazole-5-thione (xanthane hydride) does not yield carbon disulfide and cyanamide as the additional reaction products. The reaction of xanthane hydride with triphenyl phosphine or trimethyl phosphite yields triphenyl phosphine sulfide or trimethyl thiophosphate, respectively, and thiocarbamoyl isothiocyanate which has been trapped ...
