Selective and Shape??Selective Baeyer–Villiger Oxidations of Aromatic Aldehydes and Cyclic Ketones with Sn??Beta Zeolites and H2O2

…, T Blasco, A Corma, V Fornés, R Jensen…

文献索引：Renz, Michael; Blasco, Teresa; Corma, Avelino; Fornes, Vicente; Jensen, Robert; Nemeth, Laszlo Chemistry - A European Journal, 2002 , vol. 8, # 20 p. 4708 - 4717

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被引用次数: 198

摘要

Abstract Sn-Beta is used as a heterogeneous catalyst for the Baeyer–Villiger reaction with hydrogen peroxide. Cyclic ketones are transformed into the corresponding lactones, while unsaturated ketones are oxidized to the corresponding unsaturated lactones with very high chemoselectivity. The catalyst is also selective for the oxidation of aromatic aldehydes with H 2 O 2, producing the formate ester or the corresponding hydrolyzed product, that is the ...