Ring-Size Effects in the Neophyl Rearrangement. VII. 1 The Peroxide-Induced Decarbonylation of (1-Phenylcyclopropyl)-and (1-Phenylcyclobutyl) acetaldehydes

JW Wilt, LL Maravetz, JF Zawadzki

文献索引：Wilt,J.W. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 3018 - 3025

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被引用次数: 30

摘要

The syntheses of (1-phenylcyclopropy1) acetaldehyde 2 and (1-phenylcyclobuty1) acetaldehyde 3 are described in detail, together with certain other reactions of possible interest. The aldehydes were decarbonylated under freeradical conditions using di-t-butyl peroxide (DTBP) as the initiator and in several different reaction environments, uiz., neat aldehyde, aldehyde 1 M in solvent, and aldehyde in the presence of a mercaptan. The ...