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Electrical effects of cycloalkyl groups

RC Hahn, TF Corbin, H Shechter

文献索引:Hahn,R.C. et al. Journal of the American Chemical Society, 1968 , vol. 90, p. 3404 - 3415

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被引用次数: 42

摘要

Abstract: A study has been made of (1) the syntheses and ionization constants of m-and p- cyclopropyl-,-cyclobutyl,-cyclopentyl-,-cyclohexyl-,-(1-cyclopentenyl)-, and-(1-cyclohexenyl) benzoic acids and (2) the syntheses and unimalecular hydrolysis ratesof m-and p- cyclopropyl-,-cyclopentyl-,-cyclohexyl-, andp-cyclobutylphenyldimethylcarbinyl chlorides in 90% aqueous acetone. The effects of ring size on the ionization constants of the m-(1- ...